Degree Carbon
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inductive effect in 3 2 and 1 degree carbon?
why is it so that tertiary butyl shows +in effect
i am not understanding it as far as i know there is no electronegativeity difference between hydrogen and carbon then why is it so.
and why is order of decreasing inductive effect id 3 degree then 2 then 1
please
10 points sure for the best explained answer
hey gagandeep i am not asking about the case of a carbocation
look if the carbon is attached to any group and is not in form of carbocation then i am asking
An inductive effect is an electronic effect due to the polarisation of σ bonds within a molecule or ion.
This is typically due to an electronegatvity difference between the atoms at either end of the bond.
The more electronegative atom pulls the electrons in the bond towards itself creating some bond polarity.
In a simple alkyl carbocation, the positive C attracts the electrons in the σ bonds connected to that center towards itself and therefore away from the atom at the other end of the σ bond.
Electrons in C-C bonds are more readily polarised than those in a C-H bond.
Therefore, alkyl groups are better at stabilising C+ than H atoms.
So For +Inductive effect Teriary Carban> secondary-C>Primary-C> hydrogen.
All the Best.
http://rajichemworld.blogspot.com/
For your further explanation:
Electro negativity of H-2-20(paulings Scale)
Electronegativity of Carbon -2-55(Pauling scale)
So there is an electronegativity difference between H & C.
(http://en.wikipedia.org/wiki/Electronegativities_of_the_elements_(data_page) )
The inductive effect is when an electronegative atom/s in close proximity to an A-H bond makes a molecule more acidic then its counterpart lacking the electronegative atoms. Remember that the loss of a proton is an equilibrium process. Anything that makes the conjugate base more stable makes the conjugate acid stronger. Anything that destablizes the acid also makes it more acidic.
In acids which lose a proton to form an anion, this effect is primarily due to the stabilization of the conjugate base. The electronegative atom causes a slight delocalization of the negative charge. Anything that delocalizes charge makes a molecule more stable.
In cationic acids, the electronegative atom destabilizes the acid by drawing in electron density and concentrating the charge even further onto one atom. This pushes the equilibrium (relatively) in favor of proton loss.
The most basic way to explain it is that the inductive effect is used to explain how certain groups can "Push" and "Pull" charge that is next to them, the most common example is the Methyl (or similar alkyl group) that will "Push" negative charge from itself and toward whatever it is attatched to, this is called a "+I" group because of this effect. The pushing of negative charge towards something that is positive will help make that species a little less positive then if it was all alone and therefore less unstable.
This also applied to elminination and addition reactions, In early chemistry you may have done the addition of to an alkene such as Propene, although at higher levels this is described more eliquently with anti additions and such if you use the mechanism that a Br "Adds" to one of the carbons on either side of the double bond, and leaves a positive charge on the other carbon then the inductive effect plays a role in determining the most preferred place for that first Br atom to add (The least substituted place, so the inductive effect pushes charge onto the cation)
Inductive Effects: Arises from the electronegativity of the atoms in the substituent and
the polarizability of the substituent group.
Alkyl groups are polarizable and donate electron density. They exhibit electron donating inductive effect.(+I effect).
Atoms more electronegative than carbon pull electron density away from carbon.
Nitrogen, oxygen and halogens all show such a property. The electron density removal is called an electron withdrawing inductive effect.(-I effect)
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Degree Carbon
Degree Carbon